解:(Ⅰ)∵等差数列{an}的前n项和为Sn,且a3=5,S15=225,∴a1+2d=515a1+15×142d=225,解得a1=1d=2,∴an=2n-1.…(6分)(Ⅱ)∵an=2n-1,∴bn=3an+2n=32n-1+2n=13•9n+2n,∴Tn=b1+b2+…+bn=13(9+92+93+…+9n)+2(1+2+3+…+n)=13•9(1-9n)1-9+n(n+1)=38•9n+n(n+1)-38…(12分)