解：如图，∵四边形ABCD为矩形，∴∠B=∠D=∠BAD=90°，∵矩形ABCD绕点A顺时针旋转得到矩形AB′C′D′，∴∠D′=∠D=90°，∠4=α，∵∠1=∠2=110°，∴∠3=360°-90°-90°-110°=70°，∴∠4=90°-70°=20°，∴∠α=20°．故选：A．
